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dinitrogen pentoxide : ウィキペディア英語版
dinitrogen pentoxide

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Dinitrogen pentoxide is the chemical compound with the formula N2O5. Also known as nitrogen pentoxide, N2O5 is one of the binary nitrogen oxides, a family of compounds that only contain nitrogen and oxygen. It is an unstable and potentially dangerous oxidizer that once was used as a reagent when dissolved in chloroform for nitrations but has largely been superseded by NO2BF4 (nitronium tetrafluoroborate).
N2O5 is a rare example of a compound that adopts two structures depending on the conditions: most commonly it is a salt, but under some conditions it is a polar molecule:
:N2O5 (unicode:⇌) ()()
==Syntheses and properties==
N2O5 was first reported by Deville in 1840, who prepared it by treating AgNO3 with Cl2. A recommended laboratory synthesis entails dehydrating nitric acid (HNO3) with phosphorus(V) oxide:
:P4O10 + 12 HNO3 → 4 H3PO4 + 6 N2O5
In the reverse process, N2O5 reacts with water (hydrolyses) to produce nitric acid. Thus, nitrogen pentoxide is the anhydride of nitric acid:
:N2O5 + H2O → 2 HNO3
N2O5 exists as colourless crystals that sublime slightly above room temperature. The salt eventually decomposes at room temperature into NO2 and O2.


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